Product ID:MANGANESE DIOXIDE, Z134
MSDS Date:03/09/1992
FSC:6810
NIIN:00N046628
MSDS Number: BTXXW

Emergency Phone: 908-859-2151/800-424-9300(CHEMTREC)

Info Phone: 800-582-2537

Cage: HO852

Telephone: 800-582-2537

Cage: 70829

MANGANESE DIOXIDE

CAS: 1313-13-9

RTECS: OP0350000

OSHA PEL 5 MG/M3 (MN), C

ACGIH TLV: 5 MG/M3 (MN)

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: IRRIT OF UPPER
REPSIRATORY TRACT, EXCESSIVE INHALATION MAY CAUSE NAUSEA, WEAKNESS,
CHILLS, LOSS OF APPETITE, MANGANISM. SKIN: IRRITATION. EYES:
IRRITATION. INGEST: CENTRAL NERVOUS SYSTEM DEPRESSION. CHRONIC:
NONE IDENTIFIED. TARGET ORGANS: RESPIRATORY SYSTEM, CENTRAL NERVOUS
DEPRESSION, BLOOD & KIDNEYS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.

First Aid:INGEST: IF PERSON IS CONSCIOUS, IMMEDIATELY GIVE LARGE
AMOUNTS OF WATER. GET MD ATTN. INHAL: IF PERSON BREATHES IN LARGE
AMOUNTS, MOVE THE EXPOSED PERSON TO FRESH AIR. SKIN: IMMEDIATELY
WASH SKIN WITH PLENTY OF SOAP & WATER FOR AT LEAST 15MINUTES.
EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES.

Flash Point Method:CC
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP. MOVE EXPOS CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT
RISK. USE WATER TO KEEP FIRE-EXPOS CNTNRS COOL.
Unusual Fire/Explosion Hazard:STRONG OXIDIZER. CONTACT WITH COMBUSTIBLE
MATERIALS, FLAMMABLE MATERIALS OR POWDERED METALS CAN CAUSE FIRE OR
EXPLOSION.

Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. KEEP
COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL.
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY
CONTAINER & COVER; REMOVE FROM ARE A. FLUSH SPILL AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
SEPARATELY AND AWAY FROM FLAMMABLE AND COMBUSTIBLE MATERIALS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A
NIOSH/MSHA APPROVED SCBA IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKER GOGGLES .
Other Protective Equipment:UNIFORM AND APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATL TO AVOID: AZIDES, CHLORINE, CHLORATES, CHLORINE TRIFLUORIDE.

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:995F,535C
Spec Gravity:5.02 (H2O=1)
Solubility in Water:NEGLIGIBLE (<0.1%)
Appearance and Odor:BLACK CRYSTALLINE POWDER. ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG REDUCING AGENTS,NITRATES,
COMBUST MATLS, HYDROGEN PEROXIDE,(SUPP DATA)
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:NONE IDENTIFIED.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.